Issue 32, 2018

Trisiloxane-centred metal–organic frameworks and hydrogen bonded assemblies

Abstract

A hexacarboxylic acid with a trisiloxane backbone (L-H6) has been prepared and applied in MOF construction. L-H6 itself crystallizes as an unusual 2D hydrogen-bonded network. Reaction of L-H6 with Mn(II) gave IMP-20 and with Zn(II) gave IMP-21: both are 3D MOFs incorporating Si–O–Si–O–Si linkages.

Graphical abstract: Trisiloxane-centred metal–organic frameworks and hydrogen bonded assemblies

Supplementary files

Article information

Article type
Communication
Submitted
25 Apr 2018
Accepted
22 Jun 2018
First published
02 Aug 2018
This article is Open Access
Creative Commons BY license

CrystEngComm, 2018,20, 4541-4545

Trisiloxane-centred metal–organic frameworks and hydrogen bonded assemblies

L. C. Delmas, A. J. P. White, D. Pugh, P. N. Horton, S. J. Coles, P. D. Lickiss and R. P. Davies, CrystEngComm, 2018, 20, 4541 DOI: 10.1039/C8CE00662H

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