The directional character of the piperazine double addition product, e{N(CH2CH2)2N}2C60, as a building block for forming crystalline fullerene polymers

Amineh Aghabali; Sharon Jun; Marilyn M. Olmstead; Alan L. Balch

doi:10.1039/C7CE02117H

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The directional character of the piperazine double addition product, ^e{N(CH₂CH₂)₂N}₂C₆₀, as a building block for forming crystalline fullerene polymers†

Amineh Aghabali,

^a Sharon Jun,^a Marilyn M. Olmstead

*^a and Alan L. Balch

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of California, Davis, California, USA
E-mail: mmolmstead@ucdavis.edu, albalch@ucdavis.edu
Fax: +1 5307522820
Tel: +1 5307520941

Abstract

The piperazine double addition product, ^e{N(CH₂CH₂)₂N}₂C₆₀, has its donor atoms positioned to bind Lewis acids in a defined fashion in two orthogonal directions. It has been used to construct crystalline, one- and two-dimensional polymers through reactions with diiodine and the rhodium(II) acetate dimer.

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Supplementary files

Crystal structure data CIF (91K)

Article information

DOI: https://doi.org/10.1039/C7CE02117H
Article type: Paper
Submitted: 07 Dec 2017
Accepted: 15 Jan 2018
First published: 15 Jan 2018

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CrystEngComm, 2018,20, 924-929

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The directional character of the piperazine double addition product, ^e{N(CH₂CH₂)₂N}₂C₆₀, as a building block for forming crystalline fullerene polymers

A. Aghabali, S. Jun, M. M. Olmstead and A. L. Balch, CrystEngComm, 2018, 20, 924 DOI: 10.1039/C7CE02117H

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