Jump to main content
Jump to site search

Issue 6, 2018
Previous Article Next Article

Incorporating cuprous-halide clusters and lanthanide clusters to construct Heterometallic cluster organic frameworks with luminescence and gas adsorption properties

Author affiliations

Abstract

A series of heterometallic cluster organic frameworks based on cuprous-halide Cu4I4 clusters and lanthanide clusters, [Ln2(H2O)8]2(Cu4I4)(pdc)4][NO3]4·solvent (1-Ln, Ln = Y, Tb, Eu, H2pdc = 3,5-pyridinedicarboxylic acid), have been successfully synthesized under solvothermal conditions. Single-crystal X-ray diffraction analysis reveals that 1-Ln show fascinating three-dimensional porous framework structures constructed from two dissimilar types of nanosized coordination cages. Gas sorption measurements indicate that 1-Ln show moderate gas uptake capacities. The UV/vis spectroscopy measurements reveal that 1-Ln are a class of potential materials for the removal of Cr2O72− from aqueous solution. Additionally, the luminescence properties of 1-Tb and 1-Eu have also been investigated.

Graphical abstract: Incorporating cuprous-halide clusters and lanthanide clusters to construct Heterometallic cluster organic frameworks with luminescence and gas adsorption properties

Back to tab navigation

Supplementary files

Article information


Submitted
11 Nov 2017
Accepted
27 Dec 2017
First published
27 Dec 2017

CrystEngComm, 2018,20, 738-745
Article type
Paper

Incorporating cuprous-halide clusters and lanthanide clusters to construct Heterometallic cluster organic frameworks with luminescence and gas adsorption properties

J. Liu, Y. Gu, Y. Chen, Y. Qi, X. Li and S. Zheng, CrystEngComm, 2018, 20, 738
DOI: 10.1039/C7CE01963G

Social activity

Search articles by author

Spotlight

Advertisements