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Palladium-catalyzed trisallylation of benzoxazoles and 2-aryl-1,3,4-oxadiazoles with alkyne

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Abstract

A Pd-catalyzed direct C–H trisallylation of azoles with alkyne has been described. A consecutive C(sp2)–H allylation/olefin isomerization/double C(sp3)–H allylation of azoles and alkyne via a palladium catalysis system proceeds efficiently to afford the corresponding C2-alkenylated azoles containing an all quaternary carbon center.

Graphical abstract: Palladium-catalyzed trisallylation of benzoxazoles and 2-aryl-1,3,4-oxadiazoles with alkyne

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Publication details

The article was received on 19 Nov 2018, accepted on 06 Dec 2018 and first published on 06 Dec 2018


Article type: Communication
DOI: 10.1039/C8CC09165J
Citation: Chem. Commun., 2019, Advance Article
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    Palladium-catalyzed trisallylation of benzoxazoles and 2-aryl-1,3,4-oxadiazoles with alkyne

    J. Zheng, F. Hosseini-Eshbala, Y. Dong and B. Breit, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C8CC09165J

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