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Molecular tectonics: from a rigid achiral organic tecton to 3D chiral Co and Fe coordination networks

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Abstract

An achiral organic tecton bearing four coordinating sites of the pyridyl type leads to the formation of iso-structural 3D helical coordination polymers when combined with Co(SCN)2 and Fe(SCN)2 achiral neutral complexes. Their formation occurs during the self-assembly process in the solid state, which leads to crystals composed of homochiral coordination polymers.

Graphical abstract: Molecular tectonics: from a rigid achiral organic tecton to 3D chiral Co and Fe coordination networks

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Publication details

The article was received on 07 Nov 2018, accepted on 04 Dec 2018 and first published on 04 Dec 2018


Article type: Communication
DOI: 10.1039/C8CC08877B
Citation: Chem. Commun., 2019, Advance Article
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    Molecular tectonics: from a rigid achiral organic tecton to 3D chiral Co and Fe coordination networks

    P. Larpent, A. Jouaiti, N. Kyritsakas and M. W. Hosseini, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C8CC08877B

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