Issue 99, 2018

Nickel-catalysed decarbonylative borylation of aroyl fluorides

Abstract

The first Ni(cod)2/PPh3 catalyst system has been established for decarbonylative borylation of aroyl fluorides with bis(pinacolato)diboron. A wide range of functional groups in the substrates were well tolerated. The ease of access of the starting aroyl fluorides indicates that these results might become an alternative to the existing decarbonylation events.

Graphical abstract: Nickel-catalysed decarbonylative borylation of aroyl fluorides

Supplementary files

Article information

Article type
Communication
Submitted
24 Oct 2018
Accepted
20 Nov 2018
First published
20 Nov 2018

Chem. Commun., 2018,54, 13969-13972

Author version available

Nickel-catalysed decarbonylative borylation of aroyl fluorides

Z. Wang, X. Wang and Y. Nishihara, Chem. Commun., 2018, 54, 13969 DOI: 10.1039/C8CC08504H

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