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Issue 92, 2018
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Nitrosonium ion catalysis: aerobic, metal-free cross-dehydrogenative carbon–heteroatom bond formation

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Abstract

Catalytic cross-dehydrogenative coupling of heteroarenes with thiophenols and phenothiazines has been developed under mild and environmentally benign reaction conditions. For the first time, NOx+ was applied for catalytic C–S and C–N bond formation. A comprehensive scope for the C–H/S–H and C–H/N–H cross-dehydrogenative coupling was demonstrated with >60 examples. The sustainable cross-coupling conditions utilize ambient oxygen as the terminal oxidant, while water is the sole by-product.

Graphical abstract: Nitrosonium ion catalysis: aerobic, metal-free cross-dehydrogenative carbon–heteroatom bond formation

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Publication details

The article was received on 17 Oct 2018, accepted on 31 Oct 2018 and first published on 02 Nov 2018


Article type: Communication
DOI: 10.1039/C8CC08328B
Citation: Chem. Commun., 2018,54, 13022-13025
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    Nitrosonium ion catalysis: aerobic, metal-free cross-dehydrogenative carbon–heteroatom bond formation

    L. Bering, L. D’Ottavio, G. Sirvinskaite and A. P. Antonchick, Chem. Commun., 2018, 54, 13022
    DOI: 10.1039/C8CC08328B

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