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Lamellar and helical supramolecular assemblies were constructed using cucurbiturils and a naphthalenediimide derivative. More interestingly, the formation of the lamellar assembly could be reversibly photocontrolled via competitive binding with α-cyclodextrin and water-soluble azobenzene.

Graphical abstract: Photocontrolled reversible conversion of a lamellar supramolecular assembly based on cucurbiturils and a naphthalenediimide derivative

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