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Issue 98, 2018
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Moderate supercritical synthesis as a facile route to mixed-valent uranium(IV,V) and (V,VI) silicates

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Abstract

Mixed-valent uranium(IV,V) and (V,VI) phases represent a unique subset of known uranium compounds. Efforts to develop our current understanding of these materials have pointed to hydrothermal methods as effective preparative techniques. Herein we report the successful use of moderate supercritical conditions for the synthesis of five new U(V) containing phases.

Graphical abstract: Moderate supercritical synthesis as a facile route to mixed-valent uranium(iv,v) and (v,vi) silicates

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Publication details

The article was received on 28 Sep 2018, accepted on 18 Oct 2018 and first published on 18 Oct 2018


Article type: Communication
DOI: 10.1039/C8CC07789D
Citation: Chem. Commun., 2018,54, 13794-13797
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    Moderate supercritical synthesis as a facile route to mixed-valent uranium(IV,V) and (V,VI) silicates

    K. A. Pace, V. V. Klepov, G. Morrison and H. zur Loye, Chem. Commun., 2018, 54, 13794
    DOI: 10.1039/C8CC07789D

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