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Encapsulating [Mo3S13]2− clusters in cationic covalent organic frameworks: enhancing stability and recyclability by converting a homogeneous photocatalyst to a heterogeneous photocatalyst

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Abstract

We encapsulated anionic [Mo3S13]2− clusters in cationic COFs (EB-COF) to obtain the novel composite photocatalytic material Mo3S13@EB-COF. Comprehensive studies indicated that the Mo3S13@EB-COF was the product of a successful conversion of a homogeneous to a heterogeneous catalyst, and exhibited excellent stability and recyclability as well as a remarkable photocatalytic hydrogen evolution rate of 13 215 μmol g−1 h−1 under visible-light irradiation over the course of 18 hours.

Graphical abstract: Encapsulating [Mo3S13]2− clusters in cationic covalent organic frameworks: enhancing stability and recyclability by converting a homogeneous photocatalyst to a heterogeneous photocatalyst

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Publication details

The article was received on 28 Sep 2018, accepted on 06 Nov 2018 and first published on 06 Nov 2018


Article type: Communication
DOI: 10.1039/C8CC07784C
Citation: Chem. Commun., 2018, Advance Article
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    Encapsulating [Mo3S13]2− clusters in cationic covalent organic frameworks: enhancing stability and recyclability by converting a homogeneous photocatalyst to a heterogeneous photocatalyst

    Y. Cheng, R. Wang, S. Wang, X. Xi, L. Ma and S. Zang, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC07784C

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