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Issue 96, 2018
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Acid-catalyzed synthesis of functionalized arylthio cyclopropane carbaldehydes and ketones

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Abstract

A general strategy for the synthesis of arylthio cyclopropyl carbaldehydes and ketones via a Brønsted acid catalyzed arylthiol addition/ring contraction reaction sequence has been exploited. The procedure led to a wide panel of cyclopropyl carbaldehydes in generally high yields and with broad substrate scope. Mechanistic aspects and synthetic applications of this procedure were investigated.

Graphical abstract: Acid-catalyzed synthesis of functionalized arylthio cyclopropane carbaldehydes and ketones

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Publication details

The article was received on 18 Sep 2018, accepted on 12 Nov 2018 and first published on 12 Nov 2018


Article type: Communication
DOI: 10.1039/C8CC07571A
Citation: Chem. Commun., 2018,54, 13547-13550
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    Acid-catalyzed synthesis of functionalized arylthio cyclopropane carbaldehydes and ketones

    S. Porcu, A. Luridiana, A. Martis, A. Frongia, G. Sarais, D. J. Aitken, T. Boddaert, R. Guillot and F. Secci, Chem. Commun., 2018, 54, 13547
    DOI: 10.1039/C8CC07571A

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