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Issue 88, 2018
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Lock-in spin structures and ferrimagnetism in polar Ni2−xCoxScSbO6 oxides

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Abstract

The new phase Co2ScSbO6 and Ni2−xCoxScSbO6 solid solutions adopt the polar Ni3TeO6-type structure and order magnetically below 60 K. A series of long-period lock-in [0 0 1/3n] spin structures with n = 5, 6, 8 and 10 is discovered, coexisting with a ferrimagnetic [0 0 0] phase at high Co-contents. The presence of electrical polarisation and spontaneous magnetisations offers possibilities for multiferroic properties.

Graphical abstract: Lock-in spin structures and ferrimagnetism in polar Ni2−xCoxScSbO6 oxides

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Publication details

The article was received on 18 Sep 2018, accepted on 15 Oct 2018 and first published on 15 Oct 2018


Article type: Communication
DOI: 10.1039/C8CC07556E
Citation: Chem. Commun., 2018,54, 12523-12526
  • Open access: Creative Commons BY-NC license
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    Lock-in spin structures and ferrimagnetism in polar Ni2−xCoxScSbO6 oxides

    K. Ji, E. Solana-Madruga, A. M. Arevalo-Lopez, P. Manuel, C. Ritter, A. Senyshyn and J. P. Attfield, Chem. Commun., 2018, 54, 12523
    DOI: 10.1039/C8CC07556E

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