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Hollow carbon anchored highly dispersed Pd species for selective hydrogenation of 3-nitrostyrene: metal-carbon interaction

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Abstract

Constructing Pd–C bond between Pd particles and defective hollow nanocarbons (h-NCs) not only enables facile H2 dissociation but also diffusion of the dissociated H species, which makes the Pd/h-NC highly active with a TOF of 21 845 h−1 (>80 times higher than that of the best catalyst in literature), selective (97%), and stable (4 cycles) for selective hydrogenation of 3-nitrostyrene to 3-ethylnitrobenze.

Graphical abstract: Hollow carbon anchored highly dispersed Pd species for selective hydrogenation of 3-nitrostyrene: metal-carbon interaction

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Publication details

The article was received on 12 Sep 2018, accepted on 19 Oct 2018 and first published on 26 Oct 2018


Article type: Communication
DOI: 10.1039/C8CC07430E
Citation: Chem. Commun., 2018, Advance Article
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    Hollow carbon anchored highly dispersed Pd species for selective hydrogenation of 3-nitrostyrene: metal-carbon interaction

    Y. Lou, J. Xu, H. Wu and J. Liu, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC07430E

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