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Host-guest energetic materials constructed by incorporating oxidizing gas molecule into organic lattice cavity toward high-energetic and low-sensitive performance

Abstract

A promising strategy for the preparation of novel gas inclusion host-guest energetic materials was provided by incorporating powerful oxidizer N2O into the crystal lattice cavity of 2, 4, 6, 8, 10, 12-Hexanitrohexaazatetracyclododecane (HNIW). The HNIW/N2O complex crystal exhibits a surprisingly high crystallographic density (2.038 g.cm-3 at 298K), more thermal stability, better predicted detonation properties and lower sensitivity than ε-HNIW due to the enhanced packing density, improved oxidation effect and added heat-release after N2O insertion.

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Publication details

The article was received on 10 Sep 2018, accepted on 05 Dec 2018 and first published on 05 Dec 2018


Article type: Communication
DOI: 10.1039/C8CC07347C
Citation: Chem. Commun., 2018, Accepted Manuscript
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    Host-guest energetic materials constructed by incorporating oxidizing gas molecule into organic lattice cavity toward high-energetic and low-sensitive performance

    J. Xu, S. Zheng, S. Huang, Y. Tian, Y. Liu, H. Zhang and J. Sun, Chem. Commun., 2018, Accepted Manuscript , DOI: 10.1039/C8CC07347C

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