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Issue 78, 2018
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Construction of a diverse set of terpenoid decalin subunits from a common enantiomerically pure scaffold obtained by a biomimetic cationic cyclization

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Abstract

An unprecedented biomimetic cationic cyclization reaction of an alkyne-containing geraniol-derived epoxide is used for the stereoselective synthesis of a novel enantiomerically pure scaffold that is easily transformed into a set of structurally diverse decalin derivatives with potential application in the synthesis of targeted natural products and/or natural-product-inspired new molecules.

Graphical abstract: Construction of a diverse set of terpenoid decalin subunits from a common enantiomerically pure scaffold obtained by a biomimetic cationic cyclization

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Publication details

The article was received on 07 Sep 2018, accepted on 07 Sep 2018 and first published on 10 Sep 2018


Article type: Communication
DOI: 10.1039/C8CC07281G
Citation: Chem. Commun., 2018,54, 11025-11028

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    Construction of a diverse set of terpenoid decalin subunits from a common enantiomerically pure scaffold obtained by a biomimetic cationic cyclization

    R. Fontaneda, F. J. Fañanás and F. Rodríguez, Chem. Commun., 2018, 54, 11025
    DOI: 10.1039/C8CC07281G

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