Issue 82, 2018

Cu3L2 metal–organic cages for A3-coupling reactions: reversible coordination interaction triggered homogeneous catalysis and heterogeneous recovery

Abstract

The reported Cu(II) metal–organic cage (Cu3L2, 1) can be a highly active reusable catalyst to homogeneously catalyze the A3-coupling reaction in CHCl3 and can be heterogeneously recovered by simply adding 1,4-dioxane via formation of the insoluble metal–organic framework (Cu3L2(1,4-dioxane)1.5, 2).

Graphical abstract: Cu3L2 metal–organic cages for A3-coupling reactions: reversible coordination interaction triggered homogeneous catalysis and heterogeneous recovery

Supplementary files

Article information

Article type
Communication
Submitted
05 Sep 2018
Accepted
19 Sep 2018
First published
20 Sep 2018

Chem. Commun., 2018,54, 11550-11553

Cu3L2 metal–organic cages for A3-coupling reactions: reversible coordination interaction triggered homogeneous catalysis and heterogeneous recovery

G. Chen, C. Chen, X. Li, H. Ma and Y. Dong, Chem. Commun., 2018, 54, 11550 DOI: 10.1039/C8CC07208F

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