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A new strategy for constructing a disulfide-functionalized ZIF-8 analogue using structure-directing ligand–ligand covalent interaction

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Abstract

Inter-ligand van der Waals forces play a key role in the synthesis of different ZIF types. Here we report an unusual case involving covalent inter-ligand interactions through disulfide bond formation in a ZIF-8 analogue. It exhibits high CO2 uptake and stepwise adsorption of light hydrocarbons with potential applications in ethane/ethylene separation.

Graphical abstract: A new strategy for constructing a disulfide-functionalized ZIF-8 analogue using structure-directing ligand–ligand covalent interaction

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Publication details

The article was received on 30 Aug 2018, accepted on 01 Oct 2018 and first published on 10 Oct 2018


Article type: Communication
DOI: 10.1039/C8CC07064D
Citation: Chem. Commun., 2018, Advance Article
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    A new strategy for constructing a disulfide-functionalized ZIF-8 analogue using structure-directing ligand–ligand covalent interaction

    Y. Gai, X. Chen, H. Yang, Y. Wang, X. Bu and P. Feng, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC07064D

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