Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 27th March 2019 from 11:00 AM to 1:00 PM (GMT).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 82, 2018
Previous Article Next Article

Tandem one-pot CO2 reduction by PMHS and silyloxycarbonylation of aryl/vinyl halides to access carboxylic acids

Author affiliations

Abstract

The present study discloses the synthesis of aryl/vinyl carboxylic acids from Csp2-bound halides (Cl, Br, I) in a carbonylative path by using silyl formate (from CO2 and hydrosilane) as an instant CO-surrogate. Hydrosilane provides hydride for reduction and its oxidation product silanol serves as a coupling partner. Mono-, di-, and tri-carboxylic acids were obtained from the corresponding aryl/vinyl halides.

Graphical abstract: Tandem one-pot CO2 reduction by PMHS and silyloxycarbonylation of aryl/vinyl halides to access carboxylic acids

Back to tab navigation

Supplementary files

Publication details

The article was received on 22 Aug 2018, accepted on 10 Sep 2018 and first published on 27 Sep 2018


Article type: Communication
DOI: 10.1039/C8CC06820H
Citation: Chem. Commun., 2018,54, 11574-11577

  •   Request permissions

    Tandem one-pot CO2 reduction by PMHS and silyloxycarbonylation of aryl/vinyl halides to access carboxylic acids

    K. Paridala, S. Lu, M. Wang and C. Li, Chem. Commun., 2018, 54, 11574
    DOI: 10.1039/C8CC06820H

Search articles by author

Spotlight

Advertisements