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Issue 82, 2018
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Tandem one-pot CO2 reduction by PMHS and silyloxycarbonylation of aryl/vinyl halides to access carboxylic acids

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Abstract

The present study discloses the synthesis of aryl/vinyl carboxylic acids from Csp2-bound halides (Cl, Br, I) in a carbonylative path by using silyl formate (from CO2 and hydrosilane) as an instant CO-surrogate. Hydrosilane provides hydride for reduction and its oxidation product silanol serves as a coupling partner. Mono-, di-, and tri-carboxylic acids were obtained from the corresponding aryl/vinyl halides.

Graphical abstract: Tandem one-pot CO2 reduction by PMHS and silyloxycarbonylation of aryl/vinyl halides to access carboxylic acids

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Publication details

The article was received on 22 Aug 2018, accepted on 10 Sep 2018 and first published on 27 Sep 2018


Article type: Communication
DOI: 10.1039/C8CC06820H
Citation: Chem. Commun., 2018,54, 11574-11577
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    Tandem one-pot CO2 reduction by PMHS and silyloxycarbonylation of aryl/vinyl halides to access carboxylic acids

    K. Paridala, S. Lu, M. Wang and C. Li, Chem. Commun., 2018, 54, 11574
    DOI: 10.1039/C8CC06820H

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