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Issue 85, 2018
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Consecutive one-/two-step relaxation transformations of single-molecule magnets via coupling dinuclear dysprosium compounds with chloride bridges

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Abstract

The double chloride-bridged dimer of a dinuclear dysprosium(III) single-molecule magnet (SMM) was successfully isolated by assembling centrosymmetric dinuclear Dy2 SMMs. Such structural transformation involves the generation and cleavage of chloride bridges and leads to consecutive transformations of one- and two-step slow relaxation of magnetization.

Graphical abstract: Consecutive one-/two-step relaxation transformations of single-molecule magnets via coupling dinuclear dysprosium compounds with chloride bridges

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Publication details

The article was received on 17 Aug 2018, accepted on 02 Oct 2018 and first published on 02 Oct 2018


Article type: Communication
DOI: 10.1039/C8CC06699J
Citation: Chem. Commun., 2018,54, 12105-12108

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    Consecutive one-/two-step relaxation transformations of single-molecule magnets via coupling dinuclear dysprosium compounds with chloride bridges

    H. Tian, B. Wang, J. Lu, H. Liu, J. Su, D. Li and J. Dou, Chem. Commun., 2018, 54, 12105
    DOI: 10.1039/C8CC06699J

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