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Consecutive one-/two-step relaxation transformations of single-molecule magnets via coupling dinuclear dysprosium compounds with chloride bridges

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Abstract

The double chloride-bridged dimer of a dinuclear dysprosium(III) single-molecule magnet (SMM) was successfully isolated by assembling centrosymmetric dinuclear Dy2 SMMs. Such structural transformation involves the generation and cleavage of chloride bridges and leads to consecutive transformations of one- and two-step slow relaxation of magnetization.

Graphical abstract: Consecutive one-/two-step relaxation transformations of single-molecule magnets via coupling dinuclear dysprosium compounds with chloride bridges

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Publication details

The article was received on 17 Aug 2018, accepted on 02 Oct 2018 and first published on 02 Oct 2018


Article type: Communication
DOI: 10.1039/C8CC06699J
Citation: Chem. Commun., 2018, Advance Article
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    Consecutive one-/two-step relaxation transformations of single-molecule magnets via coupling dinuclear dysprosium compounds with chloride bridges

    H. Tian, B. Wang, J. Lu, H. Liu, J. Su, D. Li and J. Dou, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC06699J

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