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Issue 77, 2018
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Two-electron oxidation of a homoleptic U(III) guanidinate complex by diphenyldiazomethane

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Abstract

Reaction of the first homoleptic U(III) guanidinate complex with diphenyldiazomethane results in two-electron oxidation of U(III) to U(V) and isolation of a U(V) hydrazido complex. Corresponding U(V) imido, U(V) oxo, and U(IV) azido complexes were also synthesized for structural comparison.

Graphical abstract: Two-electron oxidation of a homoleptic U(iii) guanidinate complex by diphenyldiazomethane

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Publication details

The article was received on 09 Aug 2018, accepted on 06 Sep 2018 and first published on 12 Sep 2018


Article type: Communication
DOI: 10.1039/C8CC06514D
Citation: Chem. Commun., 2018,54, 10913-10916

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    Two-electron oxidation of a homoleptic U(III) guanidinate complex by diphenyldiazomethane

    N. S. Settineri, A. A. Shiau and J. Arnold, Chem. Commun., 2018, 54, 10913
    DOI: 10.1039/C8CC06514D

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