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Issue 82, 2018
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Local ionic liquid environment at a modified iron porphyrin catalyst enhances the electrocatalytic performance of CO2 to CO reduction in water

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Abstract

In this study we report a strategy to attach methylimidazolium fragments as ionic liquid units on an established iron porphyrin catalyst for the selective reduction of CO2 to CO. Importantly, we found that the tetra-methylimidazolium containing porphyrin exhibits an exalted electrocatalytic activity at low overpotential in water precluding the need for an external proton donor.

Graphical abstract: Local ionic liquid environment at a modified iron porphyrin catalyst enhances the electrocatalytic performance of CO2 to CO reduction in water

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Publication details

The article was received on 08 Aug 2018, accepted on 24 Sep 2018 and first published on 24 Sep 2018


Article type: Communication
DOI: 10.1039/C8CC06475J
Citation: Chem. Commun., 2018,54, 11630-11633

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    Local ionic liquid environment at a modified iron porphyrin catalyst enhances the electrocatalytic performance of CO2 to CO reduction in water

    A. Khadhraoui, P. Gotico, B. Boitrel, W. Leibl, Z. Halime and A. Aukauloo, Chem. Commun., 2018, 54, 11630
    DOI: 10.1039/C8CC06475J

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