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Issue 78, 2018
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Metallaaromatic biaryl atropisomers

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Abstract

Synthesis of stable irida-binaphthyl and -phenanthryl complexes, the first examples of metallaaromatic biaryl atropisomers, has been achieved. The combination of experimental and theoretical studies revealed that the nature of these systems is comparable to that of well-known 1,1′-binaphthalene both in terms of aromaticity and atropisomerism.

Graphical abstract: Metallaaromatic biaryl atropisomers

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Article information


Submitted
07 Aug 2018
Accepted
06 Sep 2018
First published
07 Sep 2018

Chem. Commun., 2018,54, 10974-10976
Article type
Communication

Metallaaromatic biaryl atropisomers

M. Talavera, A. Peña-Gallego, J. L. Alonso-Gómez and S. Bolaño, Chem. Commun., 2018, 54, 10974 DOI: 10.1039/C8CC06443A

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