Issue 71, 2018
From the journal:

Chemical Communications

A photocatalytic iminyl radical-mediated C–C bond cleavage/addition/cyclization cascade for the synthesis of 1,2,3,4-tetrahydrophenanthrenes†

Peng-Zi Wang,a   Xiao-Ye Yu,a   Chan-Yun Li,a   Bin-Qing He,a   Jia-Rong Chen ORCID logo *a  and  Wen-Jing Xiao ORCID logo *ab  

* Corresponding authors

a Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079, China
E-mail: chenjiarong@mail.ccnu.edu.cn, wxiao@mail.ccnu.edu.cn

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, 345 Lingling Road, Shanghai 200032, China

Abstract

On the basis of the strategy of iminyl radical-mediated C–C bond cleavage, a visible light photocatalytic radical addition/cyclization cascade is described, providing an efficient and regioselective access to cyanoalkylated 1,2,3,4-tetrahydrophenanthrenes.

Graphical abstract: A photocatalytic iminyl radical-mediated C–C bond cleavage/addition/cyclization cascade for the synthesis of 1,2,3,4-tetrahydrophenanthrenes

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Article information

DOI
https://doi.org/10.1039/C8CC06145A
Article type
Communication
Submitted
28 Jul 2018
Accepted
09 Aug 2018
First published
10 Aug 2018

Chem. Commun., 2018,54, 9925-9928

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A photocatalytic iminyl radical-mediated C–C bond cleavage/addition/cyclization cascade for the synthesis of 1,2,3,4-tetrahydrophenanthrenes

P. Wang, X. Yu, C. Li, B. He, J. Chen and W. Xiao, Chem. Commun., 2018, 54, 9925 DOI: 10.1039/C8CC06145A

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