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Issue 85, 2018
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Organosoluble tetravalent actinide di- and trifluorides

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Soluble molecular actinide(IV) fluorides can be prepared in high yield via redox or metathesis reactions of silver fluorides with actinide compounds containing ancillary iodide or fluorinated thiolate ligands. Two compounds, (py)4UF2I2·2py and (py)7Th2F5(SC6F5)3·2py were isolated and characterized by conventional methods, powder and low temperature single crystal X-ray diffraction.

Graphical abstract: Organosoluble tetravalent actinide di- and trifluorides

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The article was received on 09 Jul 2018, accepted on 02 Oct 2018 and first published on 10 Oct 2018

Article type: Communication
DOI: 10.1039/C8CC05501G
Citation: Chem. Commun., 2018,54, 12018-12020

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    Organosoluble tetravalent actinide di- and trifluorides

    G. Gotthelf, M. A. Stuber, A. Y. Kornienko, T. J. Emge and J. G. Brennan, Chem. Commun., 2018, 54, 12018
    DOI: 10.1039/C8CC05501G

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