Organosoluble tetravalent actinide di- and trifluorides

Garret Gotthelf; Matthew A. Stuber; Anna Y. Kornienko; Thomas J. Emge; John G. Brennan

doi:10.1039/C8CC05501G

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Organosoluble tetravalent actinide di- and trifluorides†

Garret Gotthelf,

^a Matthew A. Stuber,^a Anna Y. Kornienko,^a Thomas J. Emge^a and John G. Brennan

*^a

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* Corresponding authors

^a Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, 610 Taylor Road, Piscataway, NJ 08854-8087, USA
E-mail: bren@chem.rutgers.edu

Abstract

Soluble molecular actinide(IV) fluorides can be prepared in high yield via redox or metathesis reactions of silver fluorides with actinide compounds containing ancillary iodide or fluorinated thiolate ligands. Two compounds, (py)₄UF₂I₂·2py and (py)₇Th₂F₅(SC₆F₅)₃·2py were isolated and characterized by conventional methods, powder and low temperature single crystal X-ray diffraction.

This article is part of the themed collection: New molecules and materials from the f-block

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DOI: https://doi.org/10.1039/C8CC05501G
Article type: Communication
Submitted: 09 Jul 2018
Accepted: 02 Oct 2018
First published: 10 Oct 2018

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Chem. Commun., 2018,54, 12018-12020

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Organosoluble tetravalent actinide di- and trifluorides

G. Gotthelf, M. A. Stuber, A. Y. Kornienko, T. J. Emge and J. G. Brennan, Chem. Commun., 2018, 54, 12018 DOI: 10.1039/C8CC05501G

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Chemical Communications

Organosoluble tetravalent actinide di- and trifluorides†

Abstract

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Organosoluble tetravalent actinide di- and trifluorides

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