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Issue 71, 2018
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Visible-light promoted fluoroalkylselenolation: toward the reactivity of unsaturated compounds

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Abstract

The reactivity of fluoroalkylselenotoluenesulfonates with unsaturated substrates is explored herein. The direct activation of these shelf-stable reagents under visible light allows the double functionalisation of alkenes or alkynes efficiently, leading to a wide range of β-fluoroalkylselenolated sulfones. Mechanistic investigations have been undertaken supporting the formation of radical intermediates.

Graphical abstract: Visible-light promoted fluoroalkylselenolation: toward the reactivity of unsaturated compounds

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Publication details

The article was received on 30 Jun 2018, accepted on 06 Aug 2018 and first published on 06 Aug 2018


Article type: Communication
DOI: 10.1039/C8CC05256E
Citation: Chem. Commun., 2018,54, 9909-9912
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    Visible-light promoted fluoroalkylselenolation: toward the reactivity of unsaturated compounds

    C. Ghiazza, L. Khrouz, C. Monnereau, T. Billard and A. Tlili, Chem. Commun., 2018, 54, 9909
    DOI: 10.1039/C8CC05256E

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