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The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy

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Abstract

In molecular solids derived from Prussian blue, intermetallic charge transfer is fostered through a cyano bridge two metal ions. In this study, isostructural trivalent lanthanide and tetravalent actinide Prussian blue analogs’ valence orbitals are probed by soft X-ray absorption measurements.

Graphical abstract: The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy

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Publication details

The article was received on 28 Jun 2018, accepted on 25 Sep 2018 and first published on 25 Sep 2018


Article type: Communication
DOI: 10.1039/C8CC05176C
Citation: Chem. Commun., 2018, Advance Article
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    The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy

    T. Dumas, D. Guillaumont, P. Moisy, D. K. Shuh, T. Tyliszczak, P. L. Solari and C. Den Auwer, Chem. Commun., 2018, Advance Article , DOI: 10.1039/C8CC05176C

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