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Issue 71, 2018
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Metal coordination induced ring contraction of porphyrin derivatives

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Abstract

A remarkable rearrangement of a diferrocenylporphyrin to give a silver(III) corrole has been discovered. Compared to the previously reported porphyrin to corrole ring conversions (extremely rare and poor reaction yields), our methodology delivers near quantitative yield for this ring contraction.

Graphical abstract: Metal coordination induced ring contraction of porphyrin derivatives

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Submitted
12 Jun 2018
Accepted
09 Aug 2018
First published
09 Aug 2018

Chem. Commun., 2018,54, 9945-9948
Article type
Communication

Metal coordination induced ring contraction of porphyrin derivatives

B. Patra, S. Sobottka, S. Mondal, B. Sarkar and S. Kar, Chem. Commun., 2018, 54, 9945
DOI: 10.1039/C8CC04670K

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