Platinum–[diaminocarbene] complexes work as transition-metal photocatalysts for the hydrosilylation of alkynes. A catalytic system operates under visible light irradiation (blue LED) enabling the conversion of a range of terminal and internal alkynes to respective vinyl silanes in excellent yields.
![Graphical abstract: Visible light accelerated hydrosilylation of alkynes using platinum–[acyclic diaminocarbene] photocatalysts](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C8CC04287J&imageInfo.ImageIdentifier.Year=2018)
J. C. Gee, B. A. Fuller, H. Lockett, G. Sedghi, C. M. Robertson and K. V. Luzyanin, Chem. Commun., 2018, 54, 9450 DOI: 10.1039/C8CC04287J
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