Issue 68, 2018
From the journal:

Chemical Communications

Visible light accelerated hydrosilylation of alkynes using platinum–[acyclic diaminocarbene] photocatalysts†

Jack C. Gee, ORCID logo a   Beth A. Fuller,a   Hannah-Marie Lockett,a   Gita Sedghi, ORCID logo a   Craig M. Robertson ORCID logo a  and  Konstantin V. Luzyanin ORCID logo *ab  

* Corresponding authors

a Department of Chemistry, University of Liverpool, Crown Street, Liverpool, UK
E-mail: konstantin.luzyanin@liverpool.ac.uk

b Saint Petersburg State University, 7/9 Universitetskaya Nab., Saint Petersburg, Russia

Abstract

Platinum–[diaminocarbene] complexes work as transition-metal photocatalysts for the hydrosilylation of alkynes. A catalytic system operates under visible light irradiation (blue LED) enabling the conversion of a range of terminal and internal alkynes to respective vinyl silanes in excellent yields.

Graphical abstract: Visible light accelerated hydrosilylation of alkynes using platinum–[acyclic diaminocarbene] photocatalysts

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Article information

DOI
https://doi.org/10.1039/C8CC04287J
Article type
Communication
Submitted
30 May 2018
Accepted
25 Jul 2018
First published
26 Jul 2018

Chem. Commun., 2018,54, 9450-9453

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Visible light accelerated hydrosilylation of alkynes using platinum–[acyclic diaminocarbene] photocatalysts

J. C. Gee, B. A. Fuller, H. Lockett, G. Sedghi, C. M. Robertson and K. V. Luzyanin, Chem. Commun., 2018, 54, 9450 DOI: 10.1039/C8CC04287J

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