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Issue 74, 2018
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Tri(o-tolyl)phosphine for highly efficient Suzuki coupling of propargylic carbonates with boronic acids

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Abstract

A highly efficient catalytic system consisting of Pd2(dba)3·CHCl3 and tri(o-tolyl)phosphine has been identified for the coupling of propargylic carbonates with different types of organo boronic acids at room temperature. Excellent central-to-axial chirality transfer was also demonstrated.

Graphical abstract: Tri(o-tolyl)phosphine for highly efficient Suzuki coupling of propargylic carbonates with boronic acids

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Publication details

The article was received on 26 May 2018, accepted on 01 Aug 2018 and first published on 02 Aug 2018


Article type: Communication
DOI: 10.1039/C8CC04186E
Citation: Chem. Commun., 2018,54, 10451-10454

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    Tri(o-tolyl)phosphine for highly efficient Suzuki coupling of propargylic carbonates with boronic acids

    J. Xiao, H. Luo, S. Huang, H. Qian and S. Ma, Chem. Commun., 2018, 54, 10451
    DOI: 10.1039/C8CC04186E

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