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Issue 72, 2018
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{Np38} clusters: the missing link in the largest poly-oxo cluster series of tetravalent actinides

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Abstract

Two poly-oxo cluster complexes of tetravalent neptunium (Np(IV)), Np38O56Cl18(bz)24(THF)8·nTHF and Np38O56Cl42(ipa)20·mipa (bz = benzoate, THF = tetrahydrofuran, and ipa = isopropanol), were obtained via solvothermal synthesis and structurally characterised by single-crystal X-ray diffraction. The {Np38} clusters are comparable to the analogous {U38} and {Pu38} motifs, filling the gap in this largest poly-oxo cluster series of tetravalent actinides.

Graphical abstract: {Np38} clusters: the missing link in the largest poly-oxo cluster series of tetravalent actinides

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Publication details

The article was received on 09 May 2018, accepted on 12 Jul 2018 and first published on 22 Aug 2018


Article type: Communication
DOI: 10.1039/C8CC03744B
Citation: Chem. Commun., 2018,54, 10060-10063
  • Open access: Creative Commons BY-NC license
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    {Np38} clusters: the missing link in the largest poly-oxo cluster series of tetravalent actinides

    N. P. Martin, C. Volkringer, P. Roussel, J. März, C. Hennig, T. Loiseau and A. Ikeda-Ohno, Chem. Commun., 2018, 54, 10060
    DOI: 10.1039/C8CC03744B

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