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Issue 58, 2018
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A robust two-dimensional zirconium-based luminescent coordination polymer built on a V-shaped dicarboxylate ligand for vapor phase sensing of volatile organic compounds

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Abstract

We report herein a new two-dimensional zirconium-based luminescent coordination polymer Zr6(sdba)43-O)43-OH)4(HCOO)2(OH)2(H2O)2 (1) [sdba = 4,4′-sulfonyldibenzoate] exhibiting selective fluorescence responses towards a variety of volatile organic compounds upon exposure in the vapor phase. Having a unique two-dimensional signal response towards aromatic molecules, including but not limited to nitroaromatic explosives, it is capable of identifying a diverse set of analytes. In addition, compound 1 shows its remarkably high sensitivity toward acetone vapors.

Graphical abstract: A robust two-dimensional zirconium-based luminescent coordination polymer built on a V-shaped dicarboxylate ligand for vapor phase sensing of volatile organic compounds

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Publication details

The article was received on 01 May 2018, accepted on 21 Jun 2018 and first published on 22 Jun 2018


Article type: Communication
DOI: 10.1039/C8CC03496F
Citation: Chem. Commun., 2018,54, 8088-8091

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    A robust two-dimensional zirconium-based luminescent coordination polymer built on a V-shaped dicarboxylate ligand for vapor phase sensing of volatile organic compounds

    P. Du, W. P. Lustig, S. J. Teat, W. Gu, X. Liu and J. Li, Chem. Commun., 2018, 54, 8088
    DOI: 10.1039/C8CC03496F

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