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Issue 46, 2018
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Prominent hydrogenation catalysis of a PVP-stabilized Au34 superatom provided by doping a single Rh atom

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Abstract

A single rhodium atom was precisely doped into a gold cluster Au34 stabilized by poly(N-vinyl-2-pyrrolidone) (Au:PVP) as revealed by mass spectrometry. The Rh-atom-doped Au:PVP exhibited remarkable catalytic activity for hydrogenation reactions of olefins, which was much higher than that of recently reported Pd-atom-doped Au:PVP.

Graphical abstract: Prominent hydrogenation catalysis of a PVP-stabilized Au34 superatom provided by doping a single Rh atom

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Publication details

The article was received on 18 Apr 2018, accepted on 16 May 2018 and first published on 16 May 2018


Article type: Communication
DOI: 10.1039/C8CC03123A
Citation: Chem. Commun., 2018,54, 5915-5918
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    Prominent hydrogenation catalysis of a PVP-stabilized Au34 superatom provided by doping a single Rh atom

    S. Hasegawa, S. Takano, S. Yamazoe and T. Tsukuda, Chem. Commun., 2018, 54, 5915
    DOI: 10.1039/C8CC03123A

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