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Issue 46, 2018
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Bimodal coordination of fused arenes to a Pd3 cluster site

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Abstract

We report bimodal coordination behaviour of fused arenes at a Pd3 cluster site. A cyclooctatetraene-supported Pd3 cluster accommodates anthracene and tetracene in an oxidative π-addition manner, whereas triphenylene and fluoranthene are accommodated in a π-coordination manner.

Graphical abstract: Bimodal coordination of fused arenes to a Pd3 cluster site

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Publication details

The article was received on 11 Apr 2018, accepted on 14 May 2018 and first published on 22 May 2018


Article type: Communication
DOI: 10.1039/C8CC02880J
Citation: Chem. Commun., 2018,54, 5875-5878
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    Bimodal coordination of fused arenes to a Pd3 cluster site

    T. Sugawa, K. Yamamoto and T. Murahashi, Chem. Commun., 2018, 54, 5875
    DOI: 10.1039/C8CC02880J

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