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Issue 50, 2018
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Abnormal sergeants-and-soldiers effects of poly(quinoxaline-2,3-diyl)s enabling discrimination of one-carbon homologous n-alkanes through a highly sensitive solvent-dependent helix inversion

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Abstract

Poly(quinoxaline-2,3-diyl)s bearing (S)-3-octyloxymethyl and n-propoxymethyl side chains show an abnormal sergeants-and-soldiers effect in n-alkane solvents, which allows the development of a series of PQXs that exhibit an extremely sensitive solvent-dependent helix inversion that permits the discrimination of n-alkane solvents that differ by a single methylene group (e.g. n-heptane and n-octane).

Graphical abstract: Abnormal sergeants-and-soldiers effects of poly(quinoxaline-2,3-diyl)s enabling discrimination of one-carbon homologous n-alkanes through a highly sensitive solvent-dependent helix inversion

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Publication details

The article was received on 10 Apr 2018, accepted on 03 May 2018 and first published on 03 May 2018


Article type: Communication
DOI: 10.1039/C8CC02836B
Citation: Chem. Commun., 2018,54, 6867-6870
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    Abnormal sergeants-and-soldiers effects of poly(quinoxaline-2,3-diyl)s enabling discrimination of one-carbon homologous n-alkanes through a highly sensitive solvent-dependent helix inversion

    Y. Nagata, T. Nishikawa and M. Suginome, Chem. Commun., 2018, 54, 6867
    DOI: 10.1039/C8CC02836B

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