Issue 39, 2018
From the journal:

Chemical Communications

Two-step chiral transfer from d-penicillamine to metallosupramolecular ionic crystals†

Yuhei Yasukawa,a   Nobuto Yoshinari ORCID logo a  and  Takumi Konno ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan
E-mail: konno@chem.sci.osaka-u.ac.jp
Tel: +81-6-6850-5765

Abstract

Treatment of a racemic RhIII4ZnII4 complex, (Δ)4/(Λ)4-[Zn4O{Rh(aet)3}4]6+ (aet = 2-aminoethanethiolate), with D-penicillaminate (D-pen) gave optically pure ionic crystals composed of (Λ)4-[Zn4O{Rh(aet)3}4]6+ and ΛD-[Rh(D-pen)3]3−via intramolecular and intermolecular chiral transfers from D-pen.

Graphical abstract: Two-step chiral transfer from d-penicillamine to metallosupramolecular ionic crystals

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Article information

DOI
https://doi.org/10.1039/C8CC02619J
Article type
Communication
Submitted
01 Apr 2018
Accepted
23 Apr 2018
First published
24 Apr 2018

Chem. Commun., 2018,54, 5003-5006

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Two-step chiral transfer from D-penicillamine to metallosupramolecular ionic crystals

Y. Yasukawa, N. Yoshinari and T. Konno, Chem. Commun., 2018, 54, 5003 DOI: 10.1039/C8CC02619J

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