Issue 44, 2018

A lead-free perovskite-like hybrid with above-room-temperature switching of quadratic nonlinear optical properties

Abstract

We report a new lead-free perovskite-like hybrid, composed of hexamethyleneimine and one-dimensional [SbCl5]n2− polyanionic zigzag chains, which shows above-room-temperature switching of quadratic nonlinear optical (NLO) properties induced by the unique order–disorder conformational changes of the organic cation.

Graphical abstract: A lead-free perovskite-like hybrid with above-room-temperature switching of quadratic nonlinear optical properties

Supplementary files

Article information

Article type
Communication
Submitted
28 Mar 2018
Accepted
17 Apr 2018
First published
18 Apr 2018

Chem. Commun., 2018,54, 5614-5617

A lead-free perovskite-like hybrid with above-room-temperature switching of quadratic nonlinear optical properties

J. Zhang, S. Han, X. Liu, Z. Wu, C. Ji, Z. Sun and J. Luo, Chem. Commun., 2018, 54, 5614 DOI: 10.1039/C8CC02496K

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