Issue 44, 2018
From the journal:

Chemical Communications

A lead-free perovskite-like hybrid with above-room-temperature switching of quadratic nonlinear optical properties†

Jing Zhang,ab   Shiguo Han,a   Xitao Liu, ORCID logo a   Zhenyue Wu,a   Chengmin Ji,a   Zhihua Sun ORCID logo *ab  and  Junhua Luo ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China
E-mail: sunzhihua@fjirsm.ac.cn, jhluo@fjirsm.ac.cn

b College of Chemistry, Fuzhou University, Fuzhou, China

Abstract

We report a new lead-free perovskite-like hybrid, composed of hexamethyleneimine and one-dimensional [SbCl5]n2− polyanionic zigzag chains, which shows above-room-temperature switching of quadratic nonlinear optical (NLO) properties induced by the unique order–disorder conformational changes of the organic cation.

Graphical abstract: A lead-free perovskite-like hybrid with above-room-temperature switching of quadratic nonlinear optical properties

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Article information

DOI
https://doi.org/10.1039/C8CC02496K
Article type
Communication
Submitted
28 Mar 2018
Accepted
17 Apr 2018
First published
18 Apr 2018

Chem. Commun., 2018,54, 5614-5617

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A lead-free perovskite-like hybrid with above-room-temperature switching of quadratic nonlinear optical properties

J. Zhang, S. Han, X. Liu, Z. Wu, C. Ji, Z. Sun and J. Luo, Chem. Commun., 2018, 54, 5614 DOI: 10.1039/C8CC02496K

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