Visible-light and thermal driven double hydrophosphination of terminal alkynes using a commercially available iron compound

Abstract

A commercially available iron compound, [CpFe(CO)₂]₂ (1) (Cp = η⁵-C₅H₅), is an efficient catalyst for the double hydrophosphination of terminal aryl alkynes with diphenylphosphine under visible light irradiation or thermal conditions with a reduction of reaction times of up to two orders of magnitude for some substrates over literature reports. The 1,2-bis(diphenylphosphino)ethane products generated in these reactions are readily isolated in high yields.