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Issue 34, 2018
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Three-dimensional iron(ii) porous coordination polymer exhibiting carbon dioxide-dependent spin crossover

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Abstract

We report a three-dimensional Fe(II) porous coordination polymer that exhibits a spin crossover temperature change following CO2 sorption (though not N2 sorption). Furthermore, single crystals of the desolvated polymer with CO2 molecules at three different temperatures were characterised by X-ray crystallography.

Graphical abstract: Three-dimensional iron(ii) porous coordination polymer exhibiting carbon dioxide-dependent spin crossover

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Article information


Submitted
26 Jan 2018
Accepted
20 Mar 2018
First published
21 Mar 2018

Chem. Commun., 2018,54, 4262-4265
Article type
Communication

Three-dimensional iron(II) porous coordination polymer exhibiting carbon dioxide-dependent spin crossover

J. W. Shin, A. R. Jeong, S. Jeoung, H. R. Moon, Y. Komatsumaru, S. Hayami, D. Moon and K. S. Min, Chem. Commun., 2018, 54, 4262
DOI: 10.1039/C8CC00678D

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