Issue 28, 2018

Synthesis and characterization of an Fe(i) cage complex with high stability towards strong H-acids

Abstract

The first synthesized and X-ray structurally characterized “classical” iron(I) dioximate showed an unrivaled stability towards strong acids, thus calling for a reassessment of the origins of the electrocatalytic activity of similar low-valent cobalt and iron cage complexes with electron-withdrawing ribbed substituents, shown previously to be effective electrocatalysts of the HER.

Graphical abstract: Synthesis and characterization of an Fe(i) cage complex with high stability towards strong H-acids

Supplementary files

Article information

Article type
Communication
Submitted
18 Dec 2017
Accepted
31 Jan 2018
First published
31 Jan 2018

Chem. Commun., 2018,54, 3436-3439

Synthesis and characterization of an Fe(I) cage complex with high stability towards strong H-acids

Y. Z. Voloshin, V. V. Novikov, Y. V. Nelyubina, A. S. Belov, D. M. Roitershtein, A. Savitsky, A. Mokhir, J. Sutter, M. E. Miehlich and K. Meyer, Chem. Commun., 2018, 54, 3436 DOI: 10.1039/C7CC09611A

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