SCHEDULED MAINTENANCE
A diarsagermylene and a diarsastannylene stabilised by arene⋯Ge/Sn interactions†
Keith
Izod, 
*a
Peter
Evans
a
and
*a
Peter
Evans
a
and
Abstract
The synthesis and structures of two new diarsatetrylenes {(Dipp)2As}2E are presented [E = Ge, Sn; Dipp = 2,6-diisopropylphenyl]. The high barrier to planarisation of As prevents stabilisation by As–E π-interactions; however, arene⋯Ge/Sn interactions stabilise these compounds by up to 181.4 kJ mol−1. This represents a new stabilisation mode for this class of compounds.
- This article is part of the themed collection: Philip Power at 65: an icon of organometallic chemistry
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