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Issue 17, 2018

Controlling orthogonal self-assembly through cistrans isomerization of a non-covalent palladium complex dimer

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Abstract

The trans-configured square-planar complex of dichloropalladium and chiral monodentate phosphine ligands forms self-complementary dimers through 16 hydrogen bonded amides and π–π stacking in chlorinated solvents. The self-assembly is controlled by cistrans isomerisation of the metal center, where the trans-configuration governs the dimer formation.

Graphical abstract: Controlling orthogonal self-assembly through cis–trans isomerization of a non-covalent palladium complex dimer

Supplementary files

Article information


Submitted
13 Dec 2017
Accepted
29 Dec 2017
First published
02 Jan 2018

Chem. Commun., 2018,54, 2094-2097
Article type
Communication

Controlling orthogonal self-assembly through cistrans isomerization of a non-covalent palladium complex dimer

Z. Kokan, B. Kovačević, Z. Štefanić, P. Tzvetkova and S. I. Kirin, Chem. Commun., 2018, 54, 2094 DOI: 10.1039/C7CC09537F

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