Issue 10, 2018
From the journal:

Chemical Communications

A mononuclear manganese(iii)–hydroperoxo complex: synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions†

Muniyandi Sankaralingam, ORCID logo a   Yong-Min Lee, ORCID logo a   So Hyun Jeon,a   Mi Sook Seo,a   Kyung-Bin Cho ORCID logo a  and  Wonwoo Nam ORCID logo *a  

* Corresponding authors

a Department of Chemistry and Nano Science, Ewha Womans University, Seoul 03760, Korea
E-mail: wwnam@ewha.ac.kr
Fax: +82-2-3277-4114

Abstract

We report the synthesis of manganese(III)–peroxo (MnIII(O2)) and manganese(III)–hydroperoxo (MnIII(O2H)) complexes by activating dioxygen (O2) and the amphoteric reactivity of the Mn(III)–hydroperoxo complex in electrophilic and nucleophilic reactions.

Graphical abstract: A mononuclear manganese(iii)–hydroperoxo complex: synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions

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Article information

DOI
https://doi.org/10.1039/C7CC09492B
Article type
Communication
Submitted
11 Dec 2017
Accepted
07 Jan 2018
First published
08 Jan 2018

Chem. Commun., 2018,54, 1209-1212

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A mononuclear manganese(III)–hydroperoxo complex: synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions

M. Sankaralingam, Y. Lee, S. H. Jeon, M. S. Seo, K. Cho and W. Nam, Chem. Commun., 2018, 54, 1209 DOI: 10.1039/C7CC09492B

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