Ionic liquids (ILs) with trichloride anions ([Cl3]−) combined with different cations were synthesised by bringing chlorine gas into contact with the corresponding chloride (Cl−) ILs at room temperature. These trichloride ILs safely store chlorine and are useful as oxidising agents for dissolution of various metals and alloys under mild conditions.
X. Li, A. Van den Bossche, T. Vander Hoogerstraete and K. Binnemans, Chem. Commun., 2018, 54, 475 DOI: 10.1039/C7CC08645H
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