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Issue 8, 2018
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Phenylamino derivatives of tris(2-pyridylmethyl)amine: hydrogen-bonded peroxodicopper complexes

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Abstract

A series of copper complexes bearing new 6-substituted tris(2-pyridylmethyl)amine ligands (LR) appended with NH(p-R-C6H4) groups (R = H, CF3, OMe) were prepared. These ligands are electronically tunable (ΔE1/2 = 160 mV) and CuI(LR)+ complexes react with oxygen to form hydrogen bonded (trans-1,2-peroxo)dicopper species.

Graphical abstract: Phenylamino derivatives of tris(2-pyridylmethyl)amine: hydrogen-bonded peroxodicopper complexes

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Article information


Submitted
08 Nov 2017
Accepted
08 Dec 2017
First published
15 Dec 2017

Chem. Commun., 2018,54, 892-895
Article type
Communication

Phenylamino derivatives of tris(2-pyridylmethyl)amine: hydrogen-bonded peroxodicopper complexes

E. W. Dahl, H. T. Dong and N. K. Szymczak, Chem. Commun., 2018, 54, 892
DOI: 10.1039/C7CC08619A

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