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Abstract | Cited by

Room temperature isothermal reversible spin crossover switching of [Fe(H2B(pz)2)2(bipy)] thin films is demonstrated. The magnetic oxide substrate locks the [Fe{H2B(pz)2}2(bipy)] largely in a low spin state. With an X-ray fluence, excitation to a high spin state occurs, while relaxation back to low spin state is aided by alternating the substrate magnetization.

Graphical abstract: Indications of magnetic coupling effects in spin cross-over molecular thin films

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