Jump to main content
Jump to site search


Identification of traditional East Asian handmade papers through the multivariate data analysis of pyrolysis-GC/MS data

Author affiliations

Abstract

An analytical approach based on the multivariate analysis of on-line pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) data is proposed for the identification of traditional East Asian handmade papers from different fiber material origins. This approach utilized several biomarkers detected during the Py-GC/MS analysis of paper samples. At first, the total ion chromatogram (TIC) was taken as the response and then the extracted ion chromatograms (EICs) were considered to improve the discrimination of papers. The influence of different data pretreatments (raw responses vs. normalized values) including different weightings of the variables (weighting as 1 vs. weighting as 1/STD, where STD stands for standard deviation) for principal component analysis was also investigated. The results showed that compared to the commonly used microscopy techniques, the Py-GC/MS technique proved to be able to discriminate against handmade paper materials that have similar microscopic morphologies such as Morus species vs. Broussonetia species. The data pretreatment influenced PCA modeling: the analysis based on normalized values showed more interpretable PCA group features for Moraceae species. PCA without weighting resulted unsurprisingly in discrimination through the presence of high intensity response biomarkers, while when applying weight as 1/STD, a PCA loading plot was shown to provide a group of compounds, most of them being present at low levels, to be discriminating. Additionally, the characteristic EICs can provide a data matrix for statistical analysis avoiding the interference from a co-eluting compound and background compared to the data matrix obtained from the TIC. As a result, a quick Py-GC/MS based handmade paper identification procedure using PCA modeling of the characteristic EICs was proposed for the first time in the identification of traditional East Asian handmade papers. This procedure could be very beneficial for cultural heritage applications.

Graphical abstract: Identification of traditional East Asian handmade papers through the multivariate data analysis of pyrolysis-GC/MS data

Back to tab navigation

Supplementary files

Publication details

The article was received on 03 Oct 2018, accepted on 21 Nov 2018 and first published on 22 Nov 2018


Article type: Paper
DOI: 10.1039/C8AN01898G
Citation: Analyst, 2019, Advance Article
  •   Request permissions

    Identification of traditional East Asian handmade papers through the multivariate data analysis of pyrolysis-GC/MS data

    B. Han, J. Vial, S. Sakamoto and M. Sablier, Analyst, 2019, Advance Article , DOI: 10.1039/C8AN01898G

Search articles by author

Spotlight

Advertisements