Issue 3, 2017
From the journal:

Journal of Materials Chemistry C

A 3D metal–organic framework built from vanadate clusters and diamond chains showing weak ferromagnetic single-chain-magnet like behavior†

Rong Li,ab   Yu Xiao,c   Shuai-Hua Wang,*a   Xiao-Ming Jiang,a   Ying-Ying Tang,a   Jian-Gang Xu,ab   Yong Yan,ab   Fa-Kun Zheng*a  and  Guo-Cong Guo ORCID logo a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: zfk@fjirsm.ac.cn
Fax: +86 591 8371 4946
Tel: +86 591 83704827

b University of Chinese Academy of Sciences, Beijing 100039, P. R. China

c School of Pharmaceutical Science, Harbin Medical University, Harbin 150086, P. R. China

Abstract

Magnetically weakly coupled diamond chains in the 3D metal–organic framework are well separated by diamagnetic [V4O12]4− cluster units and semi-rigid ligands, and exhibit not only weak ferromagnetic interactions with frustrated spin canting but also single-chain magnets with slow magnetic relaxation below 3.4 K.

Graphical abstract: A 3D metal–organic framework built from vanadate clusters and diamond chains showing weak ferromagnetic single-chain-magnet like behavior

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Article information

DOI
https://doi.org/10.1039/C6TC04099C
Article type
Communication
Submitted
19 Sep 2016
Accepted
24 Nov 2016
First published
25 Nov 2016

J. Mater. Chem. C, 2017,5, 513-517

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A 3D metal–organic framework built from vanadate clusters and diamond chains showing weak ferromagnetic single-chain-magnet like behavior

R. Li, Y. Xiao, S. Wang, X. Jiang, Y. Tang, J. Xu, Y. Yan, F. Zheng and G. Guo, J. Mater. Chem. C, 2017, 5, 513 DOI: 10.1039/C6TC04099C

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