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Issue 8, 2017
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A fixed-bed photoreactor using conjugated nanoporous polymer-coated glass fibers for visible light-promoted continuous photoredox reactions

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Abstract

Here, we report on a fixed-bed photoreactor containing conjugated nanoporous polymer-coated glass fibers for visible light-promoted, heterogeneous photoredox reactions in a continuous flow system. A thin film of nanoporous polybenzothiadiazole with a thickness of ca. 80 nm was fabricated directly on the glass fiber with an effective catalyst content of ca. 3.2 wt%. The photocatalytic dehalogenation reaction of α-bromoacetophenones and the enantioselective α-alkylation of aldehydes were carried out in the fixed-bed photoreactor with comparable efficiencies to the state-of-art transition metal-based photocatalysts.

Graphical abstract: A fixed-bed photoreactor using conjugated nanoporous polymer-coated glass fibers for visible light-promoted continuous photoredox reactions

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Publication details

The article was received on 14 Dec 2016, accepted on 26 Jan 2017 and first published on 31 Jan 2017


Article type: Communication
DOI: 10.1039/C6TA10768K
Citation: J. Mater. Chem. A, 2017,5, 3792-3797
  • Open access: Creative Commons BY license
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    A fixed-bed photoreactor using conjugated nanoporous polymer-coated glass fibers for visible light-promoted continuous photoredox reactions

    W. Huang, B. C. Ma, D. Wang, Z. J. Wang, R. Li, L. Wang, K. Landfester and K. A. I. Zhang, J. Mater. Chem. A, 2017, 5, 3792
    DOI: 10.1039/C6TA10768K

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