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Issue 1, 2017
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Zirconocene catalyzed diastereoselective carbometalation of cyclobutenes

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Abstract

The regio- and diastereoselective zirconocene-catalyzed carbomagnesiation of cyclobutenes is herein reported to afford configurationally stable cyclobutylmagnesium species that could subsequently react with a large variety of electrophiles to give polysubstituted cyclobutane species as a single diastereoisomer.

Graphical abstract: Zirconocene catalyzed diastereoselective carbometalation of cyclobutenes

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Supplementary files

Article information


Submitted
15 Jun 2016
Accepted
04 Aug 2016
First published
30 Aug 2016

This article is Open Access
All publication charges for this article have been paid for by the Royal Society of Chemistry

Chem. Sci., 2017,8, 334-339
Article type
Edge Article
Author version available

Zirconocene catalyzed diastereoselective carbometalation of cyclobutenes

S. R. Roy, H. Eijsberg, J. Bruffaerts and I. Marek, Chem. Sci., 2017, 8, 334
DOI: 10.1039/C6SC02617F

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